In one instance, near Cauquenes, I noticed that a porphyritic conglomerate assumed a spheroidal structure, and tended to become columnar. Besides the porphyritic conglomerates and the perfectly characterised porphyries, of metamorphic origin, there are other porphyries, which, though differing not at all or only slightly in composition, certainly have had a different origin: these consist of pink or purple claystone porphyries, sometimes including grains of quartz,--of greenstone porphyry, and of other dusky rocks, all generally porphyritic with fine, large, tabular, opaque crystals, often placed crosswise, of feldspar cleaving like albite (judging from several measurements), and often amygdaloidal with silex, agate, carbonate of lime, green and brown bole. (This bole is a very common mineral in the amygdaloidal rocks; it is generally of a greenish- brown colour, with a radiating structure; externally it is black with an almost metallic lustre, but often coated by a bright green film. It is soft and can be scratched by a quill; under the blowpipe swells greatly and becomes scaly, then fuses easily into a black magnetic bead. This substance is evidently similar to that which often occurs in submarine volcanic rocks. An examination of some very curious specimens of a fine porphyry (from Jajuel) leads me to suspect that some of these amygdaloidal balls, instead of having been deposited in pre-existing air-vesicles, are of concretionary origin; for in these specimens, some of the pea-shaped little masses (often externally marked with minute pits) are formed of a mixture of green earth with stony matter, like the basis of the porphyry, including minute imperfect crystals of feldspar; and these pea-shaped little masses are themselves amygdaloidal with minute spheres of the green earth, each enveloped by a film of white, apparently feldspathic, earthy matter: so that the porphyry is doubly amygdaloidal. It should not, however, be overlooked, that all the strata here have undergone metamorphic action, which may have caused crystals of feldspar to appear, and other changes to be effected, in the originally simple amygdaloidal balls. Mr. J.D. Dana, in an excellent paper on Trap-rocks "Edinburgh New Philosophical Journal" volume 41 page 198, has argued with great force, that all amygdaloidal minerals have been deposited by aqueous infiltration. I may take this opportunity of alluding to a curious case, described in my work on "Volcanic Islands," of an amygdaloid with many of its cells only half filled up with a mesotypic mineral. M. Rose has described an amygdaloid, brought by Dr. Meyen "Reise um Erde" Th. 1. s. 316, from Chile, as consisting of crystallised quartz, with crystals of stilbite within, and lined externally by green earth.) These several porphyritic and amygdaloidal varieties never show any signs of passing into masses of sedimentary origin: they occur both in great and small intrusive masses, and likewise in strata alternating with those of the porphyritic conglomerate, and with the planes of junction often quite distinct, yet not seldom blended together. In some of these intrusive masses, the porphyries exhibit, more or less plainly, a brecciated structure, like that often seen in volcanic masses. These brecciated porphyries could generally be distinguished at once from the metamorphosed, porphyritic breccia- conglomerates, by all the fragments being angular and being formed of the same variety, and by the absence of every trace of aqueous deposition. One of the porphyries above specified, namely, the greenstone porphyry with large tabular crystals of albite, is particularly abundant, and in some parts of the Cordillera (as near St. Jago) seemed more common even than the purplish porphyritic conglomerate. Numerous dikes likewise consist of this greenstone porphyry; others are formed of various fine-grained trappean rocks; but very few of claystone porphyry: I saw no true basaltic dikes.
In several places in the lower part of the series, but not everywhere, thick masses of a highly feldspathic, often porphyritic, slaty rock occur interstratified with the porphyritic conglomerate; I believe in one or two cases blackish limestone has been found in a similar position.