Tenthly: the last and uppermost stratum here exhibited, is a compact, slate-coloured porphyry, with numerous elongated crystals of glassy feldspar, from one hundred and fifty to two hundred feet in thickness; it lies strictly conformably on the underlying conglomerate, and is undoubtedly a submarine lava.
This great pile of strata has been broken up in several places by intrusive hillocks of purple claystone porphyry, and by dikes of porphyritic greenstone: it is said that a few poor metalliferous veins have been discovered here. From the fusible nature and general appearance of the finer-grained strata, they probably owe their origin (like the allied beds of the Uspallata range, and of the Upper Patagonian tertiary formations), to gentle volcanic eruptions, and to the abrasion of volcanic rocks. Comparing these beds with those in the mining district of Arqueros, we see at both places rocks easily fusible, of the same peculiar bright green and red colours, containing calcareous matter, often having a finely brecciated structure, often passing into each other, and often alternating together: hence I cannot doubt that the only difference between them, lies in the Arqueros beds having been more metamorphosed (in conformity with their more dislocated and injected condition), and consequently in the calcareous matter, oxide of iron and green colouring matter, having been segregated under a more crystalline form.
The strata are inclined, as before stated, from 20 to 30 degrees eastward, towards an irregular north and south chain of andesitic porphyry and of porphyritic greenstone, where they are abruptly cut off. In the valley of Coquimbo, near to the H. of Gualliguaca, similar plutonic rocks are met with, apparently a southern prolongation of the above chain; and eastward of it we have an escarpment of the porphyritic conglomerate, with the strata inclined at a small angle eastward, which makes the third escarpment, including that nearest the coast. Proceeding up the valley we come to another north and south line of granite, andesite, and blackish porphyry, which seem to lie in an irregular trough of the porphyritic conglomerate. Again, on the south side of the R. Claro, there are some irregular granitic hills, which have thrown off the strata of porphyritic conglomerate to the N.W. by W.; but the stratification here has been much disturbed. I did not proceed any farther up the valley, and this point is about two-thirds of the distance between the Pacific and the main Cordillera.
I will describe only one other section, namely, on the north side of the R. Claro, which is interesting from containing fossils: the strata are much dislocated by faults and dikes, and are inclined to the north, towards a mountain of andesite and porphyry, into which they appear to become almost blended. As the beds approach this mountain, their inclination increases up to an angle of 70 degrees, and in the upper part, the rocks become highly metamorphosed. The lowest bed visible in this section, is a purplish hard sandstone. Secondly, a bed two or three hundred feet thick, of a white siliceous sandstone, with a calcareous cement, containing seams of slaty sandstone, and of hard yellowish-brown (dolomitic?) limestone; numerous, well-rounded, little pebbles of quartz are included in the sandstone. Thirdly, a dark coloured limestone with some quartz pebbles, from fifty to sixty feet in thickness, containing numerous silicified shells, presently to be enumerated. Fourthly, very compact, calcareous, jaspery sandstone, passing into (fifthly) a great bed, several hundred feet thick, of conglomerate, composed of pebbles of white, red, and purple porphyries, of sandstone and quartz, cemented by calcareous matter. I observed that some of the finer parts of this conglomerate were much indurated within a foot of a dike eight feet in width, and were rendered of a paler colour with the calcareous matter segregated into white crystallised particles; some parts were stained green from the colouring matter of the dike.