The mud, wherever I examined it, even close to the concretions, did not contain any carbonate of lime. The concretions are generally nodular, sometimes rough externally, sometimes stalactiformed; they are of a compact structure, but often penetrated (as well as the mud) by hair-like serpentine cavities, and occasionally with irregular fissures in their centres, lined with minute crystals of carbonate of lime; they are of white, brown, or pale pinkish tints, often marked by black dendritic manganese or iron; they are either darker or lighter tinted than the surrounding mass; they contain much carbonate of lime, but exhale a strong aluminous odour, and leave, when dissolved in acids, a large but varying residue, of which the greater part consists of sand. These concretions often unite into irregular strata; and over very large tracts of country, the entire mass consists of a hard, but generally cavernous marly rock: some of the varieties might be called calcareous tuffs.
Dr. Carpenter has kindly examined under the microscope, sliced and polished specimens of these concretions, and of the solid marl-rock, collected in various places between the Colorado and Santa Fe Bajada. In the greater number, Dr. Carpenter finds that the whole substance presents a tolerably uniform amorphous character, but with traces of incipient crystalline metamorphosis; in other specimens he finds microscopically minute rounded concretions of an amorphous substance (resembling in size those in oolitic rocks, but not having a concentric structure), united by a cement which is often crystalline. In some, Dr. Carpenter can perceive distinct traces of shells, corals, Polythalamia, and rarely of spongoid bodies. For the sake of comparison, I sent Dr. Carpenter specimens of the calcareous rock, formed chiefly of fragments of recent shells, from Coquimbo in Chile: in one of these specimens, Dr. Carpenter finds, besides the larger fragments, microscopical particles of shells, and a varying quantity of opaque amorphous matter; in another specimen from the same bed, he finds the whole composed of the amorphous matter, with layers showing indications of an incipient crystalline metamorphosis: hence these latter specimens, both in external appearance and in microscopical structure, closely resemble those of the Pampas. Dr. Carpenter informs me that it is well known that chemical precipitation throws down carbonate of lime in the opaque amorphous state; and he is inclined to believe that the long-continued attrition of a calcareous body in a state of crystalline or semi-crystalline aggregation (as, for instance, in the ordinary shells of Mollusca, which, when sliced, are transparent) may yield the same result. From the intimate relations between all the Coquimbo specimens, I can hardly doubt that the amorphous carbonate of lime in them has resulted from the attrition and decay of the larger fragments of shell: whether the amorphous matter in the marly rocks of the Pampas has likewise thus originated, it would be hazardous to conjecture.
For convenience' sake, I will call the marly rock by the name given to it by the inhabitants, namely, Tosca-rock; and the reddish argillaceous earth, Pampean mud. This latter substance, I may mention, has been examined for me by Professor Ehrenberg, and the result of his examination will be given under the proper localities.
I will commence my descriptions at a central spot, namely, at Buenos Ayres, and thence proceed first southward to the extreme limit of the deposit, and afterwards northward. The plain on which Buenos Ayres stands is from thirty to forty feet in height. The Pampean mud is here of a rather pale colour, and includes small nearly white nodules, and other irregular strata of an unusually arenaceous variety of tosca-rock. In a well at the depth of seventy feet, according to Ignatio Nunez, much tosca-rock was met with, and at several points, at one hundred feet deep, beds of sand have been found. I have already given a list of the recent marine and estuary shells found in many parts on the surface near Buenos Ayres, as far as three or four leagues from the Plata.