As the difference in specific gravity, caused by the different proportions of the two metals, is so exceedingly small, the separation is probably aided in a great degree by the difference in gravity between the lead, when granular though still hot, and when fluid.
In a body of liquified volcanic rock, left for some time without any violent disturbance, we might expect, in accordance with the above facts, that if one of the constituent minerals became aggregated into crystals or granules, or had been enveloped in this state from some previously existing mass, such crystals or granules would rise or sink, according to their specific gravity. Now we have plain evidence of crystals being embedded in many lavas, whilst the paste or basis has continued fluid. I need only refer, as instances, to the several, great, pseudo-porphyritic streams at the Galapagos Islands, and to the trachytic streams in many parts of the world, in which we find crystals of feldspar bent and broken by the movement of the surrounding, semi-fluid matter. Lavas are chiefly composed of three varieties of feldspar, varying in specific gravity from 2.4 to 2.74; of hornblende and augite, varying from 3.0 to 3.4; of olivine, varying from 3.3 to 3.4; and lastly, of oxides of iron, with specific gravities from 4.8 to 5.2. Hence crystals of feldspar, enveloped in a mass of liquified, but not highly vesicular lava, would tend to rise to the upper parts; and crystals or granules of the other minerals, thus enveloped, would tend to sink. We ought not, however, to expect any perfect degree of separation in such viscid materials. Trachyte, which consists chiefly of feldspar, with some hornblende and oxide of iron, has a specific gravity of about 2.45; whilst basalt, composed chiefly of augite and feldspar, often with much iron and olivine, has a gravity of about 3.0. (Trachyte from Java was found by Von Buch to be 2.47; from Auvergne, by De la Beche, it was 2.42; from Ascension, by myself, it was 2.42. Jameson and other authors give to basalt a specific gravity of 3.0; but specimens from Auvergne were found, by De la Beche, to be only 2.78; and from the Giant's Causeway, to be 2.91.) Accordingly we find, that where both trachytic and basaltic streams have proceeded from the same orifice, the trachytic streams have generally been first erupted owing, as we must suppose, to the molten lava of this series having accumulated in the upper parts of the volcanic focus. This order of eruption has been observed by Beudant, Scrope, and by other authors; three instances, also, have been given in this volume. As the later eruptions, however, from most volcanic mountains, burst through their basal parts, owing to the increased height and weight of the internal column of molten rock, we see why, in most cases, only the lower flanks of the central, trachytic masses, are enveloped by basaltic streams. The separation of the ingredients of a mass of lava, would, perhaps, sometimes take place within the body of a volcanic mountain, if lofty and of great dimensions, instead of within the underground focus; in which case, trachytic streams might be poured forth, almost contemporaneously, or at short recurrent intervals, from its summit, and basaltic streams from its base: this seems to have taken place at Teneriffe. (Consult Von Buch's well-known and admirable "Description Physique" of this island, which might serve as a model of descriptive geology.) I need only further remark, that from violent disturbances the separation of the two series, even under otherwise favourable conditions, would naturally often be prevented, and likewise their usual order of eruption be inverted. From the high degree of fluidity of most basaltic lavas, these perhaps, alone, would in many cases reach the surface.
As we have seen that crystals of feldspar, in the instance described by Von Buch, sink in obsidian, in accordance with their known greater specific gravity, we might expect to find in every trachytic district, where obsidian has flowed as lava, that it had proceeded from the upper or highest orifices.